Islamic University Journal of Applied Sciences

Magnetic Ferrite/TiO2 Nanocomposites for Enhanced Photocatalytic Water and Air Remediation

Hossameldin G., Mohamedbakr, K F. Hassan, Medhat M. El-Moselhy, Mohamed S. Thabet Zeinhom H. Mohamed and Usama. A. Soliman

Keywords: Magnetic ferrite/TiO? Nanocomposites; Photocatalysis; water remediation; Air purification; Charge separation and visible light absorption.

Major: Science

Sub Major: Solid State

https://doi.org/10.63070/jesc.2026.015; Received 16 November 2025; Revised 23 January 2026; Accepted 14 February 2026; Available online 04 March 2026.
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Abstract

Melding ferrite nanoparticles into the TiO? semiconductor lattice endows ferrite/TiO? nanocomposites, with a two?fold capability: they can be magnetically retrieved and upon light exposure they break down contaminants. This dual action directly tackles pressing woes stubborn organic pollutants lingering in water and greenhouse gases hovering in the atmosphere by sharpening charge separation and stretching light absorption deeper into the visible spectrum. Moreover, the spinel ferrite’s tunable cation arrangement reshapes both its electronic band structure and overall behavior thereby dictating efficiency and the material’s recyclability. Coating the interface with a thin protective silica layer fine?tunes charge?transfer dynamics and reinforces stability without compromising the character. The trio of TiO? polymorphs anatase, rutile and brookite each harbors distinct photocatalytic traits and their synergistic mixture typically heightens charge separation. These engineered materials are put to work breaking down dyes and pharmaceutical pollutants in water. They also serve as catalysts for photocatalytic hydrogen production through water splitting. Thanks, to their nature retrieving the catalyst is straightforward which curtails waste and trims operational expenditures. Taken together the nanocomposites chart a path toward environmental remediation and renewable power generation marrying photocatalytic prowess, with magnetic pull for straightforward recovery.

References

[1]       M. Suneetha et al., "Green Visible light catalysis for dye effluent Degradation with special reference Alizarin red and Antibacterial activity using            

       SrFe??O??/TiO?/SiO?/GO Nanocomposite," in International Conference on Bio-Based Environment for Sustainable Territory (ICBEST 2024), ed: Atlantis         Press,    2025, pp. 195-220 %@ 94-6463-648-3.

[2]       A. Khan et al., "FeSe2/TiO2 heterostructure as an efficient photocatalyst and their electrochemical energy storage applications," Materials Chemistry and Physics, vol. 303, pp. 127793 %@ 0254-0584, 2023.

[3]       E. T. Helmy, U. A. Soliman, A. M. Elbasiony, and B.-S. Nguyen, "CuCe-ferrite/TiO2 nanocomposite as an efficient magnetically separable photocatalyst for dye pollutants decolorization," Topics in Catalysis, vol. 66, no. 1, pp. 53-63, 2023.

[4]       R.-G. Ciocarlan et al., "Ferrite@ TiO2-nanocomposites as Z-scheme photocatalysts for CO2 conversion: Insight into the correlation of the Co-Zn metal composition and the catalytic activity," Journal of CO2 Utilization, vol. 36, pp. 177-186, 2020.

[5]       K. Duan et al., "A facile route to synthesize n-SnO 2/p-CuFe 2 O 4 to rapidly degrade toxic methylene blue dye under natural sunlight," RSC advances, vol. 12, no. 26, pp. 16544-16553, 2022.

[6]       A. Zielinska-Jurek et al., "Design and application of magnetic photocatalysts for water treatment. The effect of particle charge on surface functionality," Catalysts, vol. 7, no. 12, p. 360, 2017.

[7]       E. B. Lashkaryani, B. Kakavandi, R. R. Kalantary, A. J. Jafari, and M. Gholami, "Activation of peroxymonosulfate into amoxicillin degradation using cobalt ferrite nanoparticles anchored on graphene (CoFe2O4@ Gr)," Toxin Reviews, 2021.

[8]       P. Shandilya, S. Sambyal, R. Sharma, A. Kumar, and D.-V. N. Vo, "Recent advancement on ferrite based heterojunction for photocatalytic degradation of organic pollutants: a review," Ferrite: Nanostructures with tunable properties and diverse applications, pp. 121-161, 2021.

[9]       D. Balatskiy, Y. Budnikova, S. Bratskaya, and M. Vasilyeva, "TiO2-CoFe2O4 and TiO2-CuFe2O4 composite films: A new approach to synthesis, characterization, and optical and photocatalytic properties," Journal of Composites Science, vol. 7, no. 7, p. 295, 2023.

[10]     M. Golshan, B. Kakavandi, M. Ahmadi, and M. Azizi, "Photocatalytic activation of peroxymonosulfate by TiO2 anchored on cupper ferrite (TiO2@ CuFe2O4) into 2, 4-D degradation: Process feasibility, mechanism and pathway," Journal of hazardous materials, vol. 359, pp. 325-337, 2018. [Online]. Available: https://www.sciencedirect.com/science/article/abs/pii/S0304389418305090?via%3Dihub.

[11]     E. T. Helmy, M. A. Ayyad, M. A. Ali, H. G. Mohamedbakr, and J. H. Pan, "Biochemical, Histological Changes, Protein Electrophoretic Pattern, and Field Application of CuPb–Ferrite/TiO2 Nanocomposites for Controlling Terrestrial Gastropod Eobania vermiculata (Müller)," Journal of Agricultural and Food Chemistry, vol. 71, no. 17, pp. 6626-6634, 2023.

[12]     N. I. Zouli, "Photodegradation of a Broad-Spectrum Antibiotic Azithromycin Using H2O2 under Ultraviolet Irradiation," International Journal of Molecular Sciences, vol. 25, no. 12, pp. 6702 %@ 1422-0067, 2024.

[13]     T. Rahmiati, C.-C. Chen, S. A. Saad, N. Eko, and A. Apriana, "Surface Character of Magnetic Ce-doped TiO2 for Photocatalytic Performance Enhancement," Recent in Engineering Science and Technology, vol. 1, no. 01, pp. 1-6, 2023.

[14]     H. Ma and C. Liu, "A mini-review of ferrites-based photocatalyst on application of hydrogen production," Frontiers in Energy, vol. 15, no. 3, pp. 621-630, 2021.

[15]     R. Suresh, S. Rajendran, P. S. Kumar, D.-V. N. Vo, and L. Cornejo-Ponce, "RETRACTED: Recent advancements of spinel ferrite based binary nanocomposite photocatalysts in wastewater treatment," Chemosphere, vol. 274, p. 129734, 2021. [Online]. Available: https://www.sciencedirect.com/science/article/pii/S0045653521002034?via%3Dihub.

[16]     H. C. T. Firmino et al., "Nickel ferrite/TiO2 nanofibrous composite: enhanced photocatalytic dye degradation under visible light," Materials Research, vol. 27, p. e20230391, 2024.

[17]     S. Yousefi-Mohammadi, M. Movahedi, and H. Salavati, "MnCo–Ferrite/TiO2 composite as an efficient magnetically separable photocatalyst for decolorization of dye pollutants in aqueous solution," Surfaces and Interfaces, vol. 11, pp. 91-97, 2018.

[18]     M. Ahmadmoazzam, H. Akbari, A. Adibzadeh, S. Pourfadakari, and H. Akbari, "Visible-light-driven TiO2@ Fe2O3/Chitosan nanocomposite with promoted photodegradation of meropenem and imipenem antibiotics by peroxymonosulfate," Environmental Technology, vol. 45, no. 17, pp. 3456-3467, 2024.

[19]     S. Rohilla, "Rietveld refinement and structural characterization of TiO2/CoFe2O4nanocomposites," in IOP Conference Series: Materials Science and Engineering vol. 872, ed: IOP Publishing, 2020, pp. 012171 , 1757-899X.

[20]     S. Das et al., "Structural, magnetic, and dielectric behaviour of Ce3+ doped Ni-Zn ferrite/TiO2 magneto-dielectric nanocomposites," Applied Physics A, vol. 131, no. 10, pp. 1-21, 2025.

[21]     R. Peymanfar and M. Rahmanisaghieh, "Preparation of neat and capped BaFe2O4 nanoparticles and investigation of morphology, magnetic, and polarization effects on its microwave and optical performance," Materials Research Express, vol. 5, no. 10, p. 105012, 2018.

[22]     J. Zhao et al., "Lanthanum and neodymium doped barium ferrite-TiO2/MCNTs/poly (3-methyl thiophene) composites with nest structures: preparation, characterization and electromagnetic microwave absorption properties," Scientific reports, vol. 6, no. 1, p. 20496, 2016.

[23]     S. Das, G. C. Nayak, S. K. Sahu, P. C. Routray, A. K. Roy, and H. Baskey, "Titania-coated magnetite and Ni-ferrite nanocomposite-based RADAR absorbing materials for camouflaging application," Polymer-Plastics Technology and Engineering, vol. 54, no. 14, pp. 1483-1493, 2015.

[24]     L. Saini, M. K. Patra, R. K. Jani, G. K. Gupta, A. Dixit, and S. R. Vadera, "Tunable Twin Matching Frequency (f m1/f m2) Behavior of Ni1? xZnxFe2O4/NBR Composites over 2–12.4 GHz: A Strategic Material System for Stealth Applications," Scientific Reports, vol. 7, no. 1, pp. 44457 , 2045-2322, 2017.

[25]     H. Gong, "Photodegradation of pharmaceuticals with a recyclable catalyst CoFe?O?/TiO? in aqueous phase," 2018.

[26]     H. O. U. Cuiling, L. I. Tiehu, Z. Xueyun, and C. Xiaowen, "Double-layer Electromagnetic Wave Absorber Based on Carbon Nanotubes Doped with La (NO3) 3 and Fe3O4 Nanoparticles," Materials Science, vol. 23, no. 3, pp. 200-204, 2017.

[27]     S. Rohilla, "Rietveld refinement and structural characterization of TiO2/CoFe2O4nanocomposites," 2020, vol. 872: IOP Publishing, pp. 012171 , 1757-899X.

[28]     A. A. Alamri et al., "Green magnetically separable molluscicide Ba–Ce–Cu ferrite/TiO2 nanocomposite for controlling terrestrial gastropods Monacha Cartusiana," Scientific Reports, vol. 15, no. 1, p. 2888, 2025. [Online]. Available: https://www.nature.com/articles/s41598-025-85730-8.pdf.

[29]     R. Peymanfar, F. Norouzi, and S. Javanshir, "A novel approach to prepare one-pot Fe/PPy nanocomposite and evaluation of its microwave, magnetic, and optical performance," Materials Research Express, vol. 6, no. 3, p. 035024, 2018.

[30]     S. S. Rasooly, M. Anwer, and G. Tsnim, "A review on treatment methods for pesticide contaminated water," Journal of Environmental Science e, Toxicology and Food Technology, vol. 16, p. 24, 2022.

[31]     A. Rahimi, M. H. Zonoozi, R. Rahimi, and B. Zahabiyoun, "Photocatalytic activity of GO-doped bismuth-based photocatalyst for Methyl Orange decolorization under visible light irradiation," Desalination and Water Treatment, vol. 180, pp. 360-369, 2020.

[32]     A. M. Elbasiony, A. A. Alamri, U. A. Soliman, H. G. Mohamedbakr, A. M. Wahba, and E. T. Helmy, "Green synthesis of N, B co-doped TiO2 nanoparticles with enhanced photocatalytic and antioxidant activities," Journal of the Taiwan Institute of Chemical Engineers, pp. 105626 , 1876-1070, 2024.

[33]     E. E. Zaghloul, A. S. Amin, M. A. Diab, A. Elsonbati, and M. Ibrahim, "Removing 2, 4-dichlorophenoxyacetic acid (2, 4-D) from polluted water using zinc ferrite nanoparticles," Egyptian Journal of Chemistry, vol. 63, no. 4, pp. 1411-1428, 2020.

[34]     P. Jiang, Y. Yu, and K. Li, "Hydrophilic TiO2@ MWCNT/PVDF membrane for enhanced photodegradation of methyl orange in water," Fullerenes, Nanotubes and Carbon Nanostructures, vol. 31, no. 12, pp. 1185-1191, 2023.

[35]     C. Mahala, M. D. Sharma, and M. Basu, "2D nanostructures of CoFe2O4 and NiFe2O4: efficient oxygen evolution catalyst," Electrochimica Acta, vol. 273, pp. 462-473 , 0013-4686, 2018.

[36]     O. y. m. N. Avc?, L. Sementa, and A. Fortunelli, "Mechanisms of the oxygen evolution reaction on NiFe2O4 and CoFe2O4 inverse-spinel oxides," ACS catalysis, vol. 12, no. 15, pp. 9058-9073 , 2155-5435, 2022.

[37]     K. M. Gopalakrishnan, R. Ragul, K. Vallarasu, R. Anitha, and V. Vijayalakshmi, "Exploring CoFe 2 O 4/TiO 2 NCs for high-efficiency UV-driven organic dye degradation," Journal of Materials Chemistry C, vol. 13, no. 42, pp. 21561-21573, 2025.

[38]     M. Sahni et al., "Investigating the performance of CoFe2O4@ TiO2 nanomaterial as multifunctional cathode catalyst for simultaneous dye degradation and oxygen reduction in microbial desalination cell," Desalination, vol. 587, pp. 117958 , 0011-9164, 2024.

[39]     H. K. Channi and P. Kumar, "Spinel and Inverse Spinel Ferrites for Environmental Remediation," in Spinel and Inverse Spinel Ferrites: Chapman and Hall/CRC, 2025, pp. 130-149 , 1032665653.

[40]     J. Tan, W. Zhang, and A.-L. Xia, "Facile synthesis of inverse spinel NiFe2O4 nanocrystals and their superparamagnetic properties," Materials Research, vol. 16, pp. 237-241  ,1516-1439, 2013.